Research

Operando electrochemistry, electrocatalyst degradation, and quantitative electrochemical methods.

Art Deco–Cubist artwork of operando signals probing supported electrocatalysts

Operando Spectroelectrochemistry and EC-AFM

We observe electrochemical interfaces as they evolve, then connect the observed changes to activity, selectivity, and stability.

DEMS UV-vis spectroelectrochemistry EC-AFM

Core Questions

  • Which surface changes occur during operation rather than before or after testing?
  • How do structural and morphological dynamics affect catalytic output?
  • Which signals are robust enough to guide catalyst design?

Selected Papers

  • Zheng, W. ACS Electrochemistry, 2026, 2, 1127-1137
  • Chen, J., et al. Journal of Catalysis, 2024, 438, 115720
  • Zheng, W. Chemistry Methods, 2023, 3(2), e202200042
  • Zheng, W., et al. ACS Energy Letters, 2021, 6, 2838-2843
Art Deco–Cubist artwork of catalyst particles evolving across a material surface

Electrocatalyst Degradation and Stability Analysis

We investigate why catalyst performance changes over time and how active sites, supports, and electrolytes contribute to that instability.

Stability testing Interface reconstruction Selectivity tracking

Core Questions

  • Which degradation pathway dominates under realistic operating histories?
  • How can transition-metal catalysts balance activity with durability?
  • What measurements distinguish true catalyst change from measurement artifacts?

Selected Papers

  • Zheng, W. and Chen, S. JACS Au, 2025, 5, 6396-6409
  • Chen, S. and Zheng, W. Chemistry of Materials, 2026, 38, 1651-1666
  • Du, L. and Zheng, W. APL Energy, 2024, 2, 021501
Art Deco–Cubist artwork of molecular-scale electrochemical structure and transport

Quantitative Electrochemical Methods and Data Workflows

We develop practical guidance and open computational workflows for electrochemical measurements that are easy to misinterpret.

Python tools Protocol design Data standardization

Core Questions

  • Which assumptions in common electrochemical workflows are fragile?
  • How should data be processed so others can reproduce the interpretation?
  • How can computational tools reduce avoidable analysis errors?

Selected Papers

  • Zheng, W. and Du, L. ACS Energy Letters, 2024, 9, 4581-4586
  • Zheng, W. ECS Advances, 2023, 4, 040502
  • Zheng, W. ACS Energy Letters, 2023, 8, 1952-1958